'Issue with Environment Variables on VM

I am having a weird issue with Environment Variables on a VM or may be there's something that I don't know about them.

I am setting few environment variables through the Azure DevOps release pipeline using the following command.

setx NameOfEnvVar ValueOfEnvVar /m

Post completion of the release pipeline the environment variable is visible through the System Properties -> Environment Variable Window.

However, when I am running the 'set' command from the command line(as Administrator) on the VM the 'NameOfEnvVar' is not showing up.

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